Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.
Angew Chem Int Ed Engl. 2013 Mar 25;52(13):3574-83. doi: 10.1002/anie.201208189. Epub 2013 Jan 30.
The construction of boron-boron bonds, despite the intense synthetic interest in diboranes and the high B-B bond enthalpy, is still difficult, uncontrollable, and unpredictable. Methods for the construction of B-B multiple bonds are rarer still. These problems have witnessed some progress in recent years; this Minireview attempts to provide a background to the history of B-B bond synthesis and summarize the recent results in the area.
硼-硼键的构建尽管双硼烷在合成方面引起了极大的兴趣，且硼-硼键的焓值很高，但仍然具有挑战性、不可控且难以预测。构建 B-B 多重键的方法就更为罕见。近年来，这些问题取得了一些进展；本篇综述试图为硼-硼键合成的历史提供背景，并总结该领域的最新成果。
