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奥斯特瓦尔德熟化过程中再结晶材料的返回半径和体积。

Return radius and volume of recrystallized material in Ostwald ripening.

作者信息

Haußer Frank, Lakshtanov Evgeny

机构信息

Beuth Hochschule Berlin, University of Applied Sciences, Luxemburger Straße 10, 13353 Berlin, Germany.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2012 Dec;86(6 Pt 1):062601. doi: 10.1103/PhysRevE.86.062601. Epub 2012 Dec 26.

Abstract

Within the framework of the Lifshitz-Slyozov-Wagner theory of Ostwald ripening, the amount of volume of the second (solid) phase in a liquid solution that is newly formed by recrystallization is investigated. It is shown that in the late stage, the portion of the newly generated volume formed within an interval from time t(0) to t is a certain function of t/t(0) and an explicit expression of this volume is given. To achieve this, we introduce the notion of the return radius r(t,t(0)), which is the unique radius of a particle at time t(0) such that this particle has-after growing and shrinking-the same radius at time t. We derive a formula for the return radius, which later on is used to obtain the newly formed volume. Moreover, formulas for the growth rate of the return radius and the recrystallized material at time t(0) are derived.

摘要

在奥斯特瓦尔德熟化的利夫希茨-斯廖佐夫-瓦格纳理论框架内,研究了通过重结晶新形成的液相溶液中第二(固相)相的体积量。结果表明,在后期,从时间(t(0))到(t)的时间间隔内新生成的体积部分是(t/t(0))的特定函数,并给出了该体积的显式表达式。为了实现这一点,我们引入了返回半径(r(t,t(0)))的概念,它是时间(t(0))时粒子的唯一半径,使得该粒子在生长和收缩后在时间(t)时具有相同的半径。我们推导了返回半径的公式,该公式随后用于获得新形成的体积。此外,还推导了时间(t(0))时返回半径和重结晶材料的生长速率公式。

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