Effect of polymer ligand structures on fluorescence of gold clusters prepared by photoreduction.

Blue emission fluorescent Au(5) clusters with maximum quantum yield of 20.1% were synthesized by a simple photoreduction method using three specially designed tridentate polymer ligands. The evolution of fluorescent Au nanoclusters (Au NCs) under UV irradiation was studied by fluorescence, UV-Vis and X-ray photoelectron spectroscopic techniques, suggesting that the fluorescence of Au NCs is size-dependent and is associated with the presence of Au(i) ions in the Au NCs. The effect of polymer structure on the fluorescent Au NCs has also been discussed. These highly fluorescent Au NCs have potential applications in the fabrication of optoelectronic devices and light emitting materials.