Laboratorio di Scienza dei Materiali e Nanotecnologie (LMNT), D.A.D.U., CR-INSTM, Università di Sassari, Palazzo Pou Salid, Piazza Duomo 6, 07041 Alghero (SS), Italy.
Chem Soc Rev. 2013 May 7;42(9):4198-216. doi: 10.1039/c3cs35377j. Epub 2013 Feb 11.
In this review we present a short overview of the main fields of application of mesoporous ordered films obtained via templating self-assembly. These materials, because of their very special properties such as high surface area, ordered porosity, versatile functionalization of the pore surface, have been widely used for developing advanced functional applications. Mesoporous ordered films have also shown a high capability of integration in current material processing technologies also taking advantage of the high flexibility of the synthesis. A surprisingly large variety of devices and applications have been developed so far which ranges from sensors to supercapacitors and biodevices. All these applications have in common the exploitation of ordered porosity on the mesoscale and in general a strong dependence on pore topology, the nature of the pore surface and pore accessibility has been demonstrated for most of the cases. Even if a high number of examples of applications have been reported still many more are expected to come in the near future.
在这篇综述中,我们简要介绍了介孔有序薄膜在模板自组装方面的主要应用领域。由于这些材料具有高比表面积、有序多孔性、孔表面多功能化等特殊性质,因此被广泛应用于开发先进的功能应用。介孔有序薄膜还展示了在当前材料加工技术中的高度集成能力,同时也利用了合成的高灵活性。迄今为止,已经开发出了令人惊讶的多种设备和应用,从传感器到超级电容器和生物器件都有涉及。所有这些应用都共同利用了介观尺度上的有序多孔性,并且通常强烈依赖于孔拓扑结构,在大多数情况下,已经证明了孔表面的性质和孔可及性的重要性。即使已经报道了大量的应用实例,但预计在不久的将来还会有更多的应用出现。