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不同黏附载体颗粒的速水化脱硫剂在半干法 CFB-FGD 系统中的脱硫特性。

Desulfurization characteristics of rapidly hydrated sorbents with various adhesive carrier particles for a semidry CFB-FGD system.

机构信息

Key Laboratory for Thermal Science and Power Engineering of the Ministry of Education, Department of Thermal Engineering, Tsinghua University, Beijing 100084, China.

出版信息

Environ Sci Technol. 2013 Mar 19;47(6):2754-9. doi: 10.1021/es304333z. Epub 2013 Feb 28.

Abstract

Semidry flue gas desulfurization (FGD) experiments were conducted using rapidly hydrated sorbents with four different adhesive carrier particles: circulation ash from a circulating fluidized bed boiler (CFBB circulation ash), fly ash from the first electrical field of the electrostatic precipitator of a circulating fluidized bed boiler (CFBB ESP ash), fly ash from a chain boiler (chain boiler ash), and river sand smaller than 1 mm. The influences of various adhesive carrier particles and operating conditions on the desulfurization characteristics of the sorbents were investigated, including sprayed water, reaction temperature, and the ratio of calcium to sulfur (Ca/S). The experimental results indicated that the rapidly hydrated sorbents had better desulfurization characteristics by using adhesive carrier particles which possessed better pore, adhesion, and fluidization characteristics. The desulfurization efficiency of the system increased as the reaction temperature decreased, it improved from 35% to 90% as the mass flow rate of the sprayed water increased from 0 to 10 kg/h, and it increased from 65.6% to 82.7% as Ca/S increased from 1.0 to 2.0. Based on these findings, a new semidry circulating fluidized bed (CFB)-FGD system using rapidly hydrated sorbent was developed. Using the rapidly hydrated sorbent, this system uses a cyclone separator instead of an ESP or a bag filter to recycle the sorbent particles, thereby decreasing the system flow resistance, saving investment and operating costs of the solids collection equipment.

摘要

采用快速水合吸附剂进行半干法烟气脱硫(FGD)实验,使用了四种不同的粘结载体颗粒:循环流化床锅炉(CFBB)循环灰中的循环灰、CFBB 静电除尘器第一电场的粉煤灰(CFBBESP 灰)、链条锅炉的粉煤灰和小于 1mm 的河沙。研究了不同的粘结载体颗粒和操作条件对吸附剂脱硫特性的影响,包括喷雾水、反应温度和钙硫比(Ca/S)。实验结果表明,采用具有更好孔、粘附和流化特性的粘结载体颗粒,快速水合吸附剂具有更好的脱硫特性。随着反应温度的降低,脱硫效率从 35%提高到 90%,随着喷雾水质量流量从 0 增加到 10kg/h,脱硫效率从 65.6%提高到 82.7%,随着 Ca/S 从 1.0 增加到 2.0。基于这些发现,开发了一种采用快速水合吸附剂的新型半干法循环流化床(CFB)-FGD 系统。该系统采用旋风分离器代替 ESP 或袋式过滤器来回收吸附剂颗粒,从而降低系统流动阻力,节省固体收集设备的投资和运行成本。

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