Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Thermal Engineering, Tsinghua University, Beijing100084, China.
Environ Sci Technol. 2010 Jun 15;44(12):4692-6. doi: 10.1021/es903515d.
A rapidly hydrated sorbent for moderate-temperature dry flue gas desulfurization was prepared by rapidly hydrating adhesive carrier particles and lime. The circulation ash from a circulating fluidized bed boiler and chain boiler ash, both of which have rough surfaces with large specific surface areas and specific pore volumes, can improve the adhesion, abrasion resistance, and desulfurization characteristics of rapidly hydrated sorbent when used as the adhesive carrier particles. The adhesion ability of sorbent made from circulation ash is 67.4% higher than that of the existing rapidly hydrated sorbent made from fly ash, the abrasion ratio is 76.2% lower, and desulfurization ability is 14.1% higher. For sorbent made from chain boiler ash, the adhesion ability is increased by 74.7%, the desulfurization ability is increased by 30.3%, and abrasion ratio is decreased by 52.4%. The abrasion ratios of the sorbent made from circulation ash having various average diameters were all about 9%, and their desulfurization abilities were similar (approximately 150 mg/g).
一种用于中温干式烟气脱硫的快速水合吸附剂,通过快速水合胶载颗粒和石灰制备而成。循环流化床锅炉的循环灰和链条锅炉灰都具有粗糙的表面和较大的比表面积和比孔体积,可用作胶载颗粒,以提高快速水合吸附剂的附着力、耐磨性和脱硫特性。用循环灰制成的吸附剂的附着力比现有的用粉煤灰制成的快速水合吸附剂高 67.4%,耐磨性低 76.2%,脱硫能力高 14.1%。对于用链条锅炉灰制成的吸附剂,附着力提高了 74.7%,脱硫能力提高了 30.3%,耐磨性降低了 52.4%。各种平均粒径的循环灰制成的吸附剂的耐磨性均约为 9%,其脱硫能力相近(约 150mg/g)。