Faculty of Systems Engineering, Department of Opto-mechatronics, Wakayama University, 930 Sakaedani, Wakayama 640-8510, Japan.
Langmuir. 2013 Mar 5;29(9):2799-804. doi: 10.1021/la3044279. Epub 2013 Feb 19.
Chemical propulsion generates motion by directly converting locally stored chemical energy into mechanical energy. Here, we describe chemically driven autonomous motion generated by using imidazolium-based ionic liquids on a water surface. From measurements of the driving force of a locomotor loaded with an ionic liquid and observations of convection on the water surface originating from the ionic liquid container of the locomotor, the driving mechanism of the motion is found to be due to the Marangoni effect that arises from the anisotropic distribution of ionic liquids on the water surface. The maximum driving force and the force-generation duration are determined by the surface activity of the ionic liquid and the solubility of the ionic liquid in water, respectively. Because of the special properties of ionic liquids, a chemical locomotor driven by ionic liquids is promising for realizing autonomous micromachines and nanomachines that are safe and environmentally friendly.
化学推进通过直接将局部储存的化学能转化为机械能来产生运动。在这里,我们描述了通过在水面上使用基于咪唑的离子液体来产生的化学驱动自主运动。通过测量装有离子液体的运动体的驱动力,并观察源于运动体的离子液体容器的水面上的对流,可以发现运动的驱动机制是由于源自各向异性分布的 Marangoni 效应离子液体在水面上。最大驱动力和力产生持续时间分别由离子液体的表面活性和离子液体在水中的溶解度决定。由于离子液体的特殊性质,由离子液体驱动的化学运动器有望实现安全环保的自主微机器和纳米机器。