Division of Chemistry & Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371.
Chem Soc Rev. 2013 Apr 21;42(8):3222-33. doi: 10.1039/c2cs35474h.
The recent growth in graphene has witnessed the utilization of graphene as promising materials in a plethora of applications. The potential of graphene could be improved exponentially provided that the processability and band gap could be finely controlled. To this aim, chemical functionalization of graphene remains an important and fundamental approach. This tutorial review aims to provide a broad-based coverage on the recent solution-based functionalization methods of graphene in a concise and mechanistic manner. We focus on the reactions of the graphene sp(2) backbone, such as nucleophilic addition, cycloaddition, free radical additions, substitutions and rearrangements.
近年来，石墨烯的发展见证了其作为极具前景的材料在众多应用中的应用。如果能精细地控制石墨烯的加工性能和带隙，其潜力可以呈指数级增长。为此，石墨烯的化学功能化仍然是一种重要且基础的方法。本综述旨在简明而系统地介绍石墨烯的近期基于溶液的功能化方法，提供广泛的基础。我们专注于石墨烯 sp(2)骨架的反应，如亲核加成、环加成、自由基加成、取代和重排。
