在氧气和异丙醇氧化铁(II)配合物形成铁(IV)-氧配合物的自催化自由基链途径中。
An autocatalytic radical chain pathway in formation of an iron(IV)-oxo complex by oxidation of an iron(II) complex with dioxygen and isopropanol.
机构信息
Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan.
出版信息
Chem Commun (Camb). 2013 Mar 28;49(25):2500-2. doi: 10.1039/c3cc38727e.
PMID:23423328
Abstract
Evidence of an autocatalytic radical chain pathway has been reported in formation of a non-heme iron(IV)-oxo complex by oxidation of an iron(II) complex with dioxygen and isopropanol in acetonitrile at 298 K. The radical chain reaction is initiated by hydrogen abstraction from isopropanol by the iron(IV)-oxo complex.
摘要
在 298 K 下，乙腈中二氧和异丙醇氧化铁(II)配合物形成非血红素铁(IV)-氧配合物的过程中，报道了自催化自由基链途径的证据。自由基链反应由铁(IV)-氧配合物从异丙醇中提取氢引发。
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