Department of Chemistry, University of Minnesota, 207 Pleasant St SE, Minneapolis, MN 55455, USA.
Chem Commun (Camb). 2013 Apr 14;49(29):3001-3. doi: 10.1039/c3cc00013c.
Molecular modelling of an iodine(III) phenoxide was used as a starting point in the design of chiral aryl iodide catalysts for stereoselective oxidative dearomatization reactions. Using this approach, catalysts derived from 8-iodotetralone and tartaric acid were constructed and used to synthesize enantioenriched para-quinols from phenols.
碘(III)苯氧盐的分子建模被用作设计手性芳基碘催化剂用于立体选择性氧化去芳构化反应的起点。采用这种方法，构建了衍生自 8-碘四氢萘酮和酒石酸的催化剂，并将其用于从苯酚合成对映体富集的对醌醇。
