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The solution conformation of nicotinamide mononucleotide: a quantitative application of the nuclear Overhauser effect.

作者信息

Egan W, Forsén S, Jacobus J

出版信息

Biochemistry. 1975 Feb 25;14(4):735-42. doi: 10.1021/bi00675a014.

DOI:10.1021/bi00675a014
PMID:234743
Abstract

Torsion about the glycosidic linkage in nicotinamide mononucleotide has been investigated by quantitative application of the nuclear Overhauser effect. These measurements show that the syn (chi congruent to 20 degrees) and anti (chi congruent to 200 degrees) conformers of the title compound are isoenergetic, or nearly so, and interconverting rapidly. The syn/anti partition is not measurably affected by either changes in pH or temperature.

摘要

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