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链状聚[[四-双（六甲基磷酰胺-κO）双（硝酸根-κ(2) O,O'）铒（III）][银（I）-二-μ-硫代-钨酸（VI）-二-μ-硫代]]

catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κ(2) O,O')erbium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

作者信息

Wei Hongyang, Zhang Jinfang, Zhang Chi

机构信息

Institute of Molecular Engineering and Advanced Materials, School of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiaolingwei, Nanjing 210094, Jiangsu, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):m43-4. doi: 10.1107/S1600536812049987. Epub 2012 Dec 12.

DOI:10.1107/S1600536812049987
PMID:23476340
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3588238/
Abstract

In the title compound, {[Er(NO3)2(C6H18N3OP)4][AgWS4]} n , the polymeric anionic chain {AgWS4} n extends along [001]. The Er(III) atom in the cation is coordinated by eight O atoms from two bidentate nitrate anions and four hexa-methyl-phospho-ramide ligands in a distorted square-anti-prismatic geometry. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having a [WS4Ag] repeat unit. The polymeric anionic chain has a distorted linear configuration, with W-Ag-W and Ag-W-Ag angles of 161.37 (2) and 153.548 (12)°, respectively. The title complex is isotypic with the Y, Yb, Eu, Nd, La, Dy, Sm, Lu and Tb analogues.

摘要

在标题化合物{[Er(NO₃)₂(C₆H₁₈N₃OP)₄][AgWS₄]}ₙ中，聚合阴离子链{[AgWS₄]⁻}ₙ沿[001]方向延伸。阳离子中的Er(III)原子由两个双齿硝酸根阴离子的八个O原子和四个六甲基磷酰胺配体配位，呈扭曲的四方反棱柱几何构型。阳离子与两个硝酸根配体一起呈单价，这导致阴离子链具有[WS₄Ag]重复单元。聚合阴离子链具有扭曲的线性构型，W-Ag-W和Ag-W-Ag角分别为161.37 (2)°和153.548 (12)°。标题配合物与Y、Yb、Eu、Nd、La、Dy、Sm、Lu和Tb的类似物同型。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0998/3588238/3a6ae37233c4/e-69-00m43-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0998/3588238/aca5d3d30291/e-69-00m43-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0998/3588238/3a6ae37233c4/e-69-00m43-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0998/3588238/aca5d3d30291/e-69-00m43-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0998/3588238/3a6ae37233c4/e-69-00m43-fig2.jpg

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