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聚[[双-{μ2-1,2-双-[(1H-咪唑-1-基)甲基]苯}(μ4-9,10-二氧代-9,10-二氢蒽-1,4,5,8-四羧酸根合)二钴(II)]二水合物]

Poly[[bis-{μ2-1,2-bis-[(1H-imidazol-1-yl)meth-yl]benzene}(μ4-9,10-dioxo-9,10-dihydro-anthracene-1,4,5,8-tetra-carbox-yl-ato)dicobalt(II)] dihydrate].

作者信息

Sheng Xiao-Li, Xu Duo-Hui, Cai Bin, Liu Jian-Lan

机构信息

Department of Applied Chemistry, College of Science, Nanjing University of Technology, Nanjing 210009, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 1;69(Pt 3):m136. doi: 10.1107/S160053681202716X. Epub 2013 Feb 6.

DOI:10.1107/S160053681202716X
PMID:23476486
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3588523/
Abstract

The title complex, {[Co2(C18H4O10)(C14H14N4)2]·2H2O} n was synthesized from CoCl2·6H2O, 9,10-dioxo-9,10-dihydro-anthracene-1,4,5,8-tetra-carb-oxy-lic acid (H4AQTC) and 1,2-bis-[(1H-imidazol-1-yl)meth-yl]benzene (o-bix) in water. The anthraquinone unit is located about a crystallographic center of inversion. Each asymmetric unit therefore contains one Co(II) atom and one o-bix ligand, as well as half an AQTC(4-) ligand and an additional solvent water mol-ecule. The Co(II) ions are tetra-hedrally surrounded by two O atoms from two AQTC(4-) anions and by two N atoms from two o-bix ligands, forming a two-dimensional coordination polymer. The solvent water mol-ecules are connected to the carboxyl-ate groups by O-H⋯O hydrogen bonds. Additional weak C-H⋯O hydrogen bonds are observed in the crystal structure.

摘要

标题配合物{[Co₂(C₁₈H₄O₁₀)(C₁₄H₁₄N₄)₂]·2H₂O}ₙ由CoCl₂·6H₂O、9,10 - 二氧代 - 9,10 - 二氢蒽 - 1,4,5,8 - 四羧酸(H₄AQTC)和1,2 - 双[(1H - 咪唑 - 1 - 基)甲基]苯(o - bix)在水中合成。蒽醌单元位于一个晶体学反演中心周围。因此，每个不对称单元包含一个Co(II)原子和一个o - bix配体，以及半个AQTC(4 - )配体和一个额外的溶剂水分子。Co(II)离子被来自两个AQTC(4 - )阴离子的两个O原子和来自两个o - bix配体的两个N原子四面体型地包围，形成二维配位聚合物。溶剂水分子通过O - H⋯O氢键与羧酸根基团相连。在晶体结构中还观察到额外的弱C - H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b8d9/3588523/55a7780fc7ea/e-69-0m136-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b8d9/3588523/c27df3df2db5/e-69-0m136-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b8d9/3588523/55a7780fc7ea/e-69-0m136-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b8d9/3588523/c27df3df2db5/e-69-0m136-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b8d9/3588523/55a7780fc7ea/e-69-0m136-fig2.jpg

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本文引用的文献

1
Metal-organic frameworks for separations.用于分离的金属有机框架材料。
Chem Rev. 2012 Feb 8;112(2):869-932. doi: 10.1021/cr200190s. Epub 2011 Oct 6.
2
Molecule-based magnets.
Chem Soc Rev. 2011 Jun;40(6):3065-6. doi: 10.1039/c1cs90019f. Epub 2011 May 9.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.