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聚[（μ(2)-苯-1,3-二羧基-κ(2)O(1):O(3)）{μ(2)-1,2-双-[(1H-咪唑-1-基)甲基]苯-κ(2)N(3):N(3')}锌]

Poly[(μ(2)-benzene-1,3-dicarboxyl-ato-κ(2)O(1):O(3)){μ(2)-1,2-bis-[(1H-imidazol-1-yl)meth-yl]benzene-κ(2)N(3):N(3')}zinc].

作者信息

Chen Hong, Xu Heng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m826. doi: 10.1107/S1600536812022544. Epub 2012 May 26.

DOI:10.1107/S1600536812022544
PMID:22719367
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3379146/
Abstract

In the two-dimensional title coordination polymer, Zn(C(8)H(4)O(4))(C(14)H(14)N(4)), the Zn(II) atom adopts a distorted tetra-hedral geometry, being ligated by two O atoms from two different benzene-1,3-dicarboxyl-ate dianions and two N atoms from two symmetry-related 1,2-bis-(imidazol-1-ylmeth-yl)benzene mol-ecules. The dihedral angles between the imidazole rings and the benzene ring in the neutral ligand are 76.31 (13) and 85.33 (15)°. The Zn(II) atoms are bridged by dicarboxyl-ate ligands, forming chains parallel to the a axis, which are further linked by 1,2-bis-(imidazol-1-ylmeth-yl)benzene mol-ecules, generating a two-dimensional layer structure parallel to the ac plane. The crystal structure is enforced by intra-layer and inter-layer C-H⋯O hydrogen bonds.

摘要

在二维标题配位聚合物[Zn(C₈H₄O₄)(C₁₄H₁₄N₄)]ₙ中，Zn(II)原子采用扭曲的四面体几何构型，由来自两个不同苯-1,3-二羧酸二阴离子的两个O原子和来自两个对称相关的1,2-双(咪唑-1-基甲基)苯分子的两个N原子配位。中性配体中咪唑环与苯环之间的二面角为76.31 (13)°和85.33 (15)°。Zn(II)原子由二羧酸酯配体桥连，形成平行于a轴的链，这些链通过1,2-双(咪唑-1-基甲基)苯分子进一步连接，生成平行于ac平面的二维层状结构。晶体结构由层内和层间的C—H⋯O氢键加强。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b4a/3379146/dcfc262ea220/e-68-0m826-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b4a/3379146/99b9d415d0c4/e-68-0m826-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b4a/3379146/dcfc262ea220/e-68-0m826-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b4a/3379146/99b9d415d0c4/e-68-0m826-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b4a/3379146/dcfc262ea220/e-68-0m826-fig2.jpg

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本文引用的文献

1
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Dalton Trans. 2008 Mar 14(10):1302-11. doi: 10.1039/b716398c. Epub 2008 Jan 21.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.