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(丁烷-1,2,3,4-四醇-κ(3) O (1),O (2),O (3))(乙醇-κO)三(硝酸根-κ(2) O,O')钬(III)

(Butane-1,2,3,4-tetraol-κ(3) O (1),O (2),O (3))(ethanol-κO)tris-(nitrato-κ(2) O,O')holmium(III).

作者信息

Hua Xiao-Hui, Xue Jun-Hui, Yang Li-Min, Xu Yi-Zhuang, Wu Jin-Guang

机构信息

Beijing National Laboratory for Molecular Sciences, The State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 1;69(Pt 3):m162-3. doi: 10.1107/S160053681300305X. Epub 2013 Feb 20.

DOI:10.1107/S160053681300305X
PMID:23476505
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3588509/
Abstract

In the title Ho(III)-erythritol complex, [Ho(NO3)3(C4H10O4)(C2H5OH)], the Ho(III) cation is chelated by a tridentate erythritol ligand and three bidentate nitrate anions. An ethanol mol-ecule further coordinates the Ho(III) cation, completing the irregular O10 coordination geometry. In the crystal, an extensive O-H⋯O hydrogen-bond network links the mol-ecules into a three-dimensional supra-molecular structure.

摘要

在标题化合物三硝酸钬(III)-赤藓糖醇配合物[Ho(NO₃)₃(C₄H₁₀O₄)(C₂H₅OH)]中,Ho(III)阳离子由一个三齿赤藓糖醇配体和三个双齿硝酸根阴离子螯合。一个乙醇分子进一步与Ho(III)阳离子配位,形成不规则的O10配位几何构型。在晶体中,广泛的O-H⋯O氢键网络将分子连接成三维超分子结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f513/3588509/e958e49050b5/e-69-0m162-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f513/3588509/e958e49050b5/e-69-0m162-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f513/3588509/e958e49050b5/e-69-0m162-fig1.jpg

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本文引用的文献

1
Interactions between metal ions and carbohydrates. Spectroscopic characterization and the topology coordination behavior of erythritol with trivalent lanthanide ions.金属离子与碳水化合物的相互作用。赤藓糖醇与三价镧系元素离子的光谱特性及拓扑配位行为。
Inorg Chem. 2012 Jan 2;51(1):499-510. doi: 10.1021/ic2019605. Epub 2011 Dec 8.
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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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Interactions between metal ions and carbohydrates: the coordination behavior of neutral erythritol to zinc and europium nitrate.
[(2R,3S)-丁烷-1,2,3,4-四醇-κ(3)O(1),O(2),O(3)](乙醇-κO)三(硝酸根-κ(2)O,O')钐(III)
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 2;69(Pt 4):m182-3. doi: 10.1107/S1600536813003255. Print 2013 Apr 1.
金属离子与碳水化合物之间的相互作用:中性赤藓糖醇与硝酸锌和硝酸铕的配位行为。
J Inorg Biochem. 2004 Aug;98(8):1251-60. doi: 10.1016/j.jinorgbio.2004.05.012.
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Interactions between metal ions and carbohydrates. Coordination behavior of neutral erythritol to Ca(II) and lanthanide ions.金属离子与碳水化合物之间的相互作用。中性赤藓糖醇与Ca(II)和镧系离子的配位行为。
Inorg Chem. 2003 Sep 22;42(19):5844-56. doi: 10.1021/ic0300464.