State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, PR China.
Chem Commun (Camb). 2013 May 25;49(42):4746-8. doi: 10.1039/c3cc40996a.
Both neutral and cationic iridium(III) complexes containing carborane units were synthesized. Bulky carboranes can significantly improve phosphorescence quantum yields of these complexes and the electronic effect of carboranes can evidently tune emission wavelengths of cationic complexes.
合成了同时含有中性和阳离子型铱(III)配合物的含硼笼单元。大体积的硼笼可以显著提高这些配合物的磷光量子产率，而硼笼的电子效应可以明显调节阳离子配合物的发射波长。
