Chemistry Institute, The Hebrew University of Jerusalem, Jerusalem, Israel.
Phys Chem Chem Phys. 2013 May 7;15(17):6182-4. doi: 10.1039/c3cp50533b.
We report the discovery that a flow of CO2, N2 or He can sufficiently reduce the spin-spin interactions of specific stable carbon centered radicals by displacing the molecular oxygen in the atmosphere enabling their detection via electron paramagnetic resonance (EPR). This finding unlike other reported effects on carbon radicals occurs under STP conditions and is reversible.
我们报告了一个发现，即 CO2、N2 或 He 的流动可以通过取代大气中的分子氧来充分降低特定稳定碳中心自由基的自旋-自旋相互作用，从而能够通过电子顺磁共振 (EPR) 进行检测。与其他报道的碳自由基效应不同，这种现象是在 STP 条件下发生的，并且是可逆的。
