Department of Chemistry and Biochemistry, University of Oklahoma, 101 Stephenson Pkwy. Norman, OK 73019, USA.
ChemSusChem. 2013 Apr;6(4):597-9. doi: 10.1002/cssc.201200781. Epub 2013 Mar 26.
Top shelf dehydration: Ammonium perrhenate catalysts combined with benzylic alcohol reductants are used for the efficient deoxydehydration of glycols to olefins. The olefin and aldehyde products can be easily separated and isolated. It is also demonstrated that the catalyst can be recovered and reused because of its low solubility in aromatic solvents.
过铼酸铵催化剂与苄醇还原剂结合使用，可高效将二醇脱氧脱水为烯烃。烯烃和醛产物可轻松分离和隔离。此外，由于该催化剂在芳烃溶剂中的溶解度低，因此可以回收和重复使用。
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