Institute for Complex Molecular Systems and Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
Chem Commun (Camb). 2013 Jun 21;49(49):5532-4. doi: 10.1039/c3cc41636d.
Cooperative aggregation of monomers into one-dimensional nanostructures typically results in elongated objects. Here we analyse in depth the self-assembly of an N-monoarylated perylene bisimide which shows characteristics of a cooperative growth mechanism but unexpectedly yields objects of small size, due to anti-cooperativity by attenuated growth.
单体协同聚集形成一维纳米结构通常会导致生成细长的物体。在这里，我们深入分析了 N-单芳基取代的苝二酰亚胺的自组装，它表现出协同生长机制的特征，但由于生长减弱的反协同作用，出乎意料地产生了小尺寸的物体。
