State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China.
Chem Commun (Camb). 2013 May 7;49(35):3658-60. doi: 10.1039/c3cc41237g. Epub 2013 Mar 27.
A giant metallo-supramolecular cage encapsulating a single-molecule magnet, [Ag42{Ho(W5O18)2}(t-BuC≡C)28Cl4]OH, is prepared and structurally characterized. It shows an interesting "peanut-like" structure and remains intact in solution as demonstrated by NMR studies.
一种巨型金属超分子笼包裹着一个单分子磁体，[Ag42{Ho(W5O18)2}(t-BuC≡C)28Cl4]OH，被制备并进行了结构表征。它呈现出一种有趣的“花生状”结构，并且在溶液中保持完整，这一点通过 NMR 研究得到了证明。
