Department of Inorganic Chemistry and Technology, Jožef Stefan Institute, Jamova 39, SI-1000 Ljubljana, Slovenia.
Inorg Chem. 2013 Apr 15;52(8):4319-23. doi: 10.1021/ic302323j. Epub 2013 Mar 29.
The reactions between compounds of the type MAF6 (M = alkali metal; A = P, As, V, Ru, Ir, Sb, Nb, Ta) and xenon difluoride were studied in anhydrous hydrogen fluoride solvent. The coordination products [M(XeF2)n]AsF6 were only observed in the case of LiAF6 (A = P, As, Ru, Ir), and the crystal structure of [Li(XeF2)3]AsF6 was determined (monoclinic space group P21 with a = 6.901(9) Å, b = 13.19(2) Å, c = 6.91(1) Å, β = 91.84(2)°, and Z = 2). The coordination sphere of lithium is comprised of six F atoms. The compound series was also characterized by Raman spectroscopy.
研究了类型为 MAF6（M = 碱金属；A = P、As、V、Ru、Ir、Sb、Nb、Ta）的化合物与氙二氟化物在无水氟化氢溶剂中的反应。仅在 LiAF6（A = P、As、Ru、Ir）的情况下观察到配位产物[M(XeF2)n]AsF6，并且确定了[Li(XeF2)3]AsF6 的晶体结构（单斜空间群 P21，a = 6.901(9) Å，b = 13.19(2) Å，c = 6.91(1) Å，β = 91.84(2)°，Z = 2）。锂离子的配位球由六个 F 原子组成。该化合物系列还通过拉曼光谱进行了表征。
