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多糖基表面活性剂在有机改性粘土颗粒水悬浮液中的应用。

Use of polysaccharide based surfactants to stabilize organically modified clay particles aqueous dispersion.

机构信息

Institute for Engineering Materials and Design, University of Maribor, Smetanova ul. 17, SI-2000 Maribor, Slovenia.

出版信息

Carbohydr Polym. 2013 Apr 15;94(1):687-94. doi: 10.1016/j.carbpol.2013.01.085. Epub 2013 Feb 4.

Abstract

Pure as well as organically modified clay minerals are widely applied particles in different research areas. For the incorporation of hydrophobic organically modified clay particles into the hydrogel matrix, a stable aqueous dispersion must be prepared. In this article we report on the stabilization of aqueous dispersions of hydrophobic organically modified clay particles by using a non-ionic polysaccharide-based surfactant system-Inutec SP1 (based on chicory inulin). Different concentrations of surfactants were tested. Properties of the particulate surfactant-stabilized aqueous colloidal system were determined by electrophoretic mobility and dynamic light scattering measurements. Determination of contact angles gave us insight into the particles' surface interaction ability with water and also some information regarding the conformation of adsorbed surfactant molecules on the particle surface. By using Inutec SP1, the wettability of clay particles was improved, particle size was reduced and consequently, enhancement of their dispersion ability in water-based systems was observed.

摘要

纯粘土矿物和有机改性粘土矿物是广泛应用于不同研究领域的颗粒。为了将疏水性有机改性粘土颗粒掺入水凝胶基质中,必须制备稳定的水基分散体。本文报道了通过使用非离子多糖基表面活性剂体系-Inutec SP1(基于菊苣菊糖)稳定疏水性有机改性粘土颗粒的水基分散体。测试了不同浓度的表面活性剂。通过电泳迁移率和动态光散射测量来确定颗粒状表面活性剂稳定的水性胶体系统的性质。接触角的测定使我们了解了颗粒与水的表面相互作用能力,并且还提供了有关吸附在颗粒表面上的表面活性剂分子构象的一些信息。通过使用 Inutec SP1,可以改善粘土颗粒的润湿性,减小颗粒尺寸,从而观察到它们在水基体系中的分散能力增强。

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