Laboratoire de Physique Théorique et Modèles Statistiques, CNRS et Université Paris-Sud 11, UMR8626, 91405 Orsay Cedex, France.
J Chem Phys. 2013 Mar 28;138(12):12A540. doi: 10.1063/1.4776213.
We discuss the slow relaxation phenomenon in glassy systems by means of replicas by constructing a static field theory approach to the problem. At the mean field level we study how criticality in the four point correlation functions arises because of the presence of soft modes and we derive an effective replica field theory for these critical fluctuations. By using this at the gaussian level we obtain many physical quantities: the correlation length, the exponent parameter that controls the mode-coupling dynamical exponents for the two-point correlation functions, and the prefactor of the critical part of the four point correlation functions. Moreover, we perform a one-loop computation in order to identify the region in which the mean field gaussian approximation is valid. The result is a Ginzburg criterion for the glass transition. We define and compute in this way a proper Ginzburg number. Finally, we present numerical values of all these quantities obtained from the hypernetted chain approximation for the replicated liquid theory.
我们通过构造静态场理论方法来讨论玻璃态系统中的缓慢弛豫现象。在平均场水平上,我们研究了由于软模式的存在而如何在四点相关函数中出现临界点,并为这些临界涨落推导出有效的副本场理论。通过在高斯水平上使用它,我们得到了许多物理量:相关长度、控制两点相关函数的模式耦合动力学指数的指数参数,以及四点相关函数的临界部分的前因子。此外,我们进行了单圈计算,以确定平均场高斯近似有效的区域。结果是玻璃化转变的吉布斯判据。我们以这种方式定义并计算了适当的吉布斯数。最后,我们从复制液体理论的超网链逼近中得到了所有这些量的数值。