Department of Chemistry, Queen's University, Kingston, Ontario, K7L 3N6, Canada.
Angew Chem Int Ed Engl. 2013 Apr 22;52(17):4544-8. doi: 10.1002/anie.201300873. Epub 2013 Apr 5.
Highly fluorescent π-conjugated polycyclic azaborines can be prepared from B,N-heterocyclic compounds with a BR2 -CH2 unit through the elimination of an R-H molecule (see scheme). These clean photoelimination reactions occur both in solution and in polymers doped with the precursors.
高度荧光的π共轭多环氮硼杂环化合物可以通过带有 BR2 -CH2 单元的 B,N-杂环化合物消除 R-H 分子来制备(见方案)。这些清洁的光消除反应既可以在溶液中进行,也可以在掺杂前体的聚合物中进行。