碳纳米管对水溶液中染料的吸附去除:综述。
Adsorptive removal of dyes from aqueous solution onto carbon nanotubes: a review.
机构信息
Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee, 247 667, India.
出版信息
Adv Colloid Interface Sci. 2013 Jun;193-194:24-34. doi: 10.1016/j.cis.2013.03.003. Epub 2013 Mar 25.
Adsorption is a widely used technique for the separation and removal of pollutants from wastewaters. Carbon nanotubes (CNTs) are emerging as potential adsorbents because of its well defined cylindrical hollow structure, large surface area, high aspect ratios, hydrophobic wall and easily modified surfaces. In this review, dye adsorption capability of CNTs and CNT based composites from aqueous system has been compiled. This article provides the information about the defect, adsorption sites on CNTs and batch adsorption studies under the influence of various operational parameters such as contact time, solution pH, temperatures etc. and deals with mechanisms involved in adsorption of dyes onto CNTs. From the literature reviewed, it is observed that single walled carbon nanotubes (SWCNTs) show higher adsorption capacity than multi walled carbon nanotubes (MWCNTs) and functionalized and CNT composite have better sorption capacity than as grown CNTs. It is evident from the literature that CNT based nanosorbents have shown good potential for the removal of dyes from aqueous solution. However, still more research work should be focused on the development of cost effective, higher efficient and environmental friendly CNT based nanosorbents for their commercial applications.
吸附是一种广泛应用于从废水中分离和去除污染物的技术。由于其具有定义明确的圆柱状中空结构、大表面积、高纵横比、疏水性壁和易于修饰的表面,碳纳米管 (CNT) 作为一种潜在的吸附剂而崭露头角。本综述总结了 CNT 及其基于 CNT 的复合材料从水相中吸附染料的能力。本文提供了有关 CNT 上缺陷和吸附位点的信息,并在各种操作参数(如接触时间、溶液 pH 值、温度等)的影响下进行了批量吸附研究,并涉及了染料在 CNT 上吸附的机制。从综述的文献中可以看出,单壁碳纳米管 (SWCNT) 的吸附容量高于多壁碳纳米管 (MWCNT),功能化 CNT 及其复合材料的吸附容量高于原生 CNT。文献表明,基于 CNT 的纳米吸附剂在从水溶液中去除染料方面表现出良好的潜力。然而,仍然需要更多的研究工作来专注于开发具有成本效益、更高效率和环境友好型的基于 CNT 的纳米吸附剂,以实现其商业应用。