Center of Eco-material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China.
J Environ Sci (China). 2013 Feb 1;25(2):246-53. doi: 10.1016/s1001-0742(12)60031-x.
Kapok fibers have been acetylated for oil spill cleanup in the aqueous environment. The structures of raw and acetylated kapok fiber were characterized using Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM). Without severe damage to the lumen structures, the kapok fibers were successfully acetylated and the resulting fibers exhibited a better oil sorption capacity than raw fibers for diesel and soybean oil. Compared with high viscosity soybean oil, low viscosity diesel shows a better affinity to the surface of acetylated fibers. Sorption kinetics is fitted well by the pseudo second-order model, and the equilibrium data can be described by the Freundlich isotherm model. The results implied that acetylated kapok fiber can be used as the substitute for non-biodegradable oil sorption materials.
木棉纤维已被乙酰化,可用于水相环境中的溢油清理。使用傅里叶变换红外(FT-IR)光谱和扫描电子显微镜(SEM)对原棉纤维和乙酰化棉纤维的结构进行了表征。在不对腔结构造成严重破坏的情况下,成功地对木棉纤维进行了乙酰化处理,并且所得纤维对柴油和大豆油的吸附能力优于原纤维。与高粘度的大豆油相比,低粘度的柴油对乙酰化纤维表面具有更好的亲和力。吸附动力学很好地符合拟二级模型,平衡数据可以用 Freundlich 等温模型来描述。结果表明,乙酰化木棉纤维可用作不可生物降解的吸油材料的替代品。