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木棉接枝甲基丙烯酸丁酯的制备及其吸油性

Preparation and oil absorbency of kapok-g-butyl methacrylate.

作者信息

Wang Jintao, Zheng Yian, Wang Aiqin

机构信息

a Center of Eco-material and Green Chemistry , Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences , Lanzhou , People's Republic of China.

b College of Materials Science and Engineering , Beifang University of Nationalities , Yinchuan , People's Republic of China.

出版信息

Environ Technol. 2018 May;39(9):1089-1095. doi: 10.1080/09593330.2017.1321689. Epub 2017 May 5.

Abstract

Butyl methacrylate (BMA) was grafted onto kapok fiber using benzoyl peroxide (BPO) as initiator. The structure of the grafted kapok was investigated using Fourier transform infrared spectroscopy and scanning electron microscopy. The results illustrated that BMA was successfully grafted onto the kapok fiber surface. The effects of monomer concentration, temperature and time on the oil absorbency of grafted kapok fiber were investigated. The oil absorbencies of raw kapok, NaClO-treated kapok fiber and kapok-g-butyl methacrylate were evaluated and compared. Compared with raw kapok fiber, grafted kapok fiber showed the highest oil absorbency, with the increase percentage of 63.4%, 42.5% and 56.4% for chloroform, toluene and n-hexane, respectively. Furthermore, the as-developed grafted kapok fiber exhibited excellent reusability, and can be utilized as an eco-friendly material for recovering oil released into the surroundings.

摘要

以过氧化苯甲酰(BPO)为引发剂,将甲基丙烯酸丁酯(BMA)接枝到木棉纤维上。采用傅里叶变换红外光谱和扫描电子显微镜对接枝木棉的结构进行了研究。结果表明,BMA成功接枝到木棉纤维表面。研究了单体浓度、温度和时间对接枝木棉纤维吸油率的影响。对原生木棉、次氯酸钠处理的木棉纤维和接枝甲基丙烯酸丁酯的木棉的吸油率进行了评估和比较。与原生木棉纤维相比,接枝木棉纤维的吸油率最高,对氯仿、甲苯和正己烷的吸油率分别提高了63.4%、42.5%和56.4%。此外,所制备的接枝木棉纤维具有优异的可重复使用性,可作为一种环保材料用于回收泄漏到环境中的油。

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