Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan.
Org Lett. 2013 May 3;15(9):2112-5. doi: 10.1021/ol400574s. Epub 2013 Apr 22.
It has been established that a cationic Rh(I)/dppf complex catalyzes the olefin isomerization/allyl Claisen rearrangement/intramolecular hydroacylation cascade of di(allyl) ethers to produce substituted cyclopentanones in good yields under mild conditions.
已经确定，一种阳离子 Rh(I)/dppf 配合物可以在温和条件下催化二烯丙基醚的烯烃异构化/烯丙基克莱森重排/分子内氢酰化级联反应，以高产率生成取代的环戊酮。
