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Cu 掺杂 V2O5 花状结构作为高性能锂离子电池的正极材料。

Cu doped V2O5 flowers as cathode material for high-performance lithium ion batteries.

机构信息

School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore.

出版信息

Nanoscale. 2013 Jun 7;5(11):4937-43. doi: 10.1039/c3nr00548h. Epub 2013 Apr 29.

Abstract

Hierarchical Cu doped vanadium pentoxide (V2O5) flowers were prepared via a simple hydrothermal approach followed by an annealing process. The flower precursors are self-assembled with 1D nanobelts surrounding a central core. The morphological evolution is investigated and a plausible mechanism is proposed. As the cathode material for lithium ion batteries, the Cu doped V2O5 samples exhibit improved electrochemical performance compared to the un-doped ones. Among them Cu0.02V1.98O5 delivered higher reversible specific capacities, better cycling stabilities and excellent rate capabilities, e.g. 97 mA h g(-1) at 20.0 C.

摘要

通过简单的水热法和随后的退火处理,制备了分层的 Cu 掺杂五氧化二钒(V2O5)花。花前体是由围绕中心核的一维纳米带自组装而成的。研究了形态演变,并提出了一种合理的机制。作为锂离子电池的阴极材料,与未掺杂的相比,Cu 掺杂的 V2O5 样品表现出了改善的电化学性能。其中,Cu0.02V1.98O5 表现出更高的可逆比容量、更好的循环稳定性和优异的倍率性能,例如在 20.0 C 时为 97 mA h g(-1)。

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