• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

聚[二水合-[μ6-4,4'-(1,4-亚苯基)双-(2,6-二甲基吡啶-3,5-二羧酸根合)]二铅(II)]

Poly[diaqua-[μ6-4,4'-(1,4-phenyl-ene)bis-(2,6-dimethyl-pyridine-3,5-dicarboxyl-ato)]dilead(II)].

作者信息

Zhu Yi, Zhang Ming-Xing, Yang Shan-Shan, Xiao Feng, Zhang Xiao-Ping, Gao Yuan-Yuan, Li Bing-Jie, Huang Kun-Lin

机构信息

College of Life Science, and College of Chemistry, Chongqing Normal University, Chongqing 400047, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 28;69(Pt 4):m232-3. doi: 10.1107/S1600536813007733. Print 2013 Apr 1.

DOI:10.1107/S1600536813007733
PMID:23634022
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3629504/
Abstract

The asymmetric unit of the title Pb-based coordination polymer, [Pb2(C24H16N2O8)(H2O)2] n , consists of one Pb(II) cation, half of a 4,4'-(1,4-phenyl-ene)bis-(2,6-dimethyl-pyridine-3,5-di-carb-oxyl-ate (L (4-)) ligand and one coordinating water mol-ecule. The centers of the benzene ring of the ligand and the four-membered Pb/O/Pb/O ring are located on centers of inversion. The Pb(II) ion is coordinated in form of a distorted polyhedron by seven O atoms from four separate L (4-) ligands and by one water O atom. The PbO7 polyhedra share O atoms, forming infinite zigzag [PbO4(H2O)] n chains along [100] that are bridged by L (4-) ligands, forming a two-dimensional coordination network parallel to (001). O-H⋯O hydrogen bonds involving the water mol-ecule are observed.

摘要

标题为[Pb2(C24H16N2O8)(H2O)2] n的铅基配位聚合物的不对称单元由一个Pb(II)阳离子、半个4,4'-(1,4-亚苯基)双-(2,6-二甲基吡啶-3,5-二羧酸酯 (L (4-))配体和一个配位水分子组成。配体苯环的中心和四元Pb/O/Pb/O环位于对称中心上。Pb(II)离子由来自四个独立L (4-)配体的七个O原子和一个水分子O原子以扭曲多面体的形式配位。PbO7多面体共享O原子，沿着[100]形成无限之字形[PbO4(H2O)] n链，这些链由L (4-)配体桥连，形成平行于(001)的二维配位网络。观察到涉及水分子的O-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e94/3629504/889ffd1b6609/e-69-0m232-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e94/3629504/1d830a308b0a/e-69-0m232-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e94/3629504/94af867755d5/e-69-0m232-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e94/3629504/d894a635e74e/e-69-0m232-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e94/3629504/889ffd1b6609/e-69-0m232-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e94/3629504/1d830a308b0a/e-69-0m232-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e94/3629504/94af867755d5/e-69-0m232-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e94/3629504/d894a635e74e/e-69-0m232-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e94/3629504/889ffd1b6609/e-69-0m232-fig4.jpg

相似文献

1
Poly[diaqua-[μ6-4,4'-(1,4-phenyl-ene)bis-(2,6-dimethyl-pyridine-3,5-dicarboxyl-ato)]dilead(II)].聚[二水合-[μ6-4,4'-(1,4-亚苯基)双-(2,6-二甲基吡啶-3,5-二羧酸根合)]二铅(II)]
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 28;69(Pt 4):m232-3. doi: 10.1107/S1600536813007733. Print 2013 Apr 1.
2
Poly[[μ-aqua-diaqua-bis-(μ-furan-2,5-dicarboxyl-ato-κ(2) O (2):O (5))bis-(1,10-phenanthroline-κ(2) N,N')dicopper(II)] N,N-dimethyl-formamide monosolvate].聚[[μ-水-二水-双-(μ-呋喃-2,5-二羧酸根-κ(2) O(2):O(5))双-(1,10-菲咯啉-κ(2) N,N')二铜(II)]] N,N-二甲基甲酰胺单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Dec 1;68(Pt 12):m1484-5. doi: 10.1107/S1600536812046041. Epub 2012 Nov 14.
3
Poly[diaqua-(μ(4)-2,5-dicarb-oxy-benzene-1,4-dicarboxyl-ato-κ(4)O(1):O(2):O(4):O(5))(μ(2)-2,5-dicarb-oxy-benzene-1,4-dicarboxyl-ato-κ(2)O(1):O(4))bis-(1,10-phenanthroline-κ(2)N,N')dimanganese(II)].聚[二水合-(μ(4)-2,5-二羧基苯-1,4-二羧酸根合-κ(4)O(1):O(2):O(4):O(5))(μ(2)-2,5-二羧基苯-1,4-二羧酸根合-κ(2)O(1):O(4))双-(1,10-菲咯啉-κ(2)N,N')二锰(II)]
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1184-5. doi: 10.1107/S1600536812035441. Epub 2012 Aug 23.
4
catena-Poly[[aqua-(1,10-phenanthroline)cadmium(II)]-μ-benzene-1,4-di-carboxyl-ato].链状聚[[水合-(1,10-菲咯啉)镉(II)]-μ-苯-1,4-二羧酸根]
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 17;65(Pt 1):m90. doi: 10.1107/S1600536808041913.
5
catena-Poly[[[aqua-(pyridine-2,6-dicarboxyl-ato N-oxide-κO,O)cobalt(II)]-μ-1,3-di-4-pyridylpropane-κN:N'] dihydrate].
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 18;64(Pt 11):m1415-6. doi: 10.1107/S1600536808032741.
6
Phenyl-hydrazinium (6-carb-oxy-pyridine-2-carboxyl-ato)(pyridine-2,6-dicarboxyl-ato)cobaltate(II)-pyridine-2,6-dicarb-oxy-lic acid-water (1/1/3).苯基肼基（6 - 羧基吡啶 - 2 - 羧基）（吡啶 - 2,6 - 二羧基）钴（II） - 吡啶 - 2,6 - 二羧酸 - 水（1/1/3）
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 24;66(Pt 12):m1643-4. doi: 10.1107/S1600536810048191.
7
Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxyl-ato)-μ(3)-(pyridine-2,6-dicarboxyl-ato)-cobalt(II)disodium].聚[二-μ(2)-水-μ(5)-(吡啶-2,6-二羧酸根)-μ(3)-(吡啶-2,6-二羧酸根)-钴(II)二钠]
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1782-3. doi: 10.1107/S1600536811048252. Epub 2011 Nov 19.
8
Poly[μ(3)-hydroxido-μ-(pyridine-2,4,6-tricarboxyl-ato)-dilead(II)].聚[μ(3)-羟基-μ-(吡啶-2,4,6-三羧酸根)-二铅(II)]
Acta Crystallogr Sect E Struct Rep Online. 2010 Dec 4;67(Pt 1):m15-6. doi: 10.1107/S1600536810049275.
9
catena-Poly[[[diaqua-iron(II)]-μ-pyridine-2,5-dicarboxyl-ato-[tetra-aqua-iron(II)]-μ-pyridine-2,5-dicarboxyl-ato] tetra-hydrate].链状聚[[[二水合铁（II）]-μ-吡啶-2,5-二羧酸根-[四水合铁（II）]-μ-吡啶-2,5-二羧酸根]四水合物]
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 25;64(Pt 2):m413. doi: 10.1107/S1600536808002043.
10
Dimethyl-ammonium diaqua-(pyridine-2,4-dicarboxyl-ato-κN,O)cuprate(II).二甲基铵二水合-（吡啶-2,4-二羧酸根-κN,O）铜（II）
Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 27;66(Pt 2):m206-7. doi: 10.1107/S1600536810002497.

本文引用的文献

1
Distinct chiral units from an axially prochiral ligand in a photoluminescent zinc(II)-organic complex.光致发光锌（II）有机配合物中来自轴向前手性配体的不同手性单元。
Acta Crystallogr C. 2012 Apr;68(Pt 4):m90-3. doi: 10.1107/S0108270112006051. Epub 2012 Mar 3.
2
A binuclear zinc polymer with paddlewheel building units and intersecting helical chains based on a flexible 4-[(carboxymethyl)sulfanyl]benzoic acid ligand.
Acta Crystallogr C. 2011 Oct;67(Pt 10):m324-6. doi: 10.1107/S0108270111032811. Epub 2011 Sep 15.
3
The pervasive chemistry of metal-organic frameworks.金属有机框架材料的广泛化学性质。
Chem Soc Rev. 2009 May;38(5):1213-4. doi: 10.1039/b903811f. Epub 2009 Apr 1.
4
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
5
The Reticular Chemistry Structure Resource (RCSR) database of, and symbols for, crystal nets.晶体网络的网状化学结构资源（RCSR）数据库及符号
Acc Chem Res. 2008 Dec;41(12):1782-9. doi: 10.1021/ar800124u.
6
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
7
Structural variation from 1D to 3D: effects of ligands and solvents on the construction of lead(II)-organic coordination polymers.从一维到三维的结构变化：配体和溶剂对铅（II）-有机配位聚合物构建的影响
Chemistry. 2007;13(11):3248-61. doi: 10.1002/chem.200600730.
8
Polyhapto-aromatic interactions in lead(II) coordination.铅（II）配位中的多齿-芳香族相互作用。
Inorg Chem. 2004 Mar 22;43(6):1810-2. doi: 10.1021/ic034835x.
9
A nanotubular 3D coordination polymer based on a 3d-4f heterometallic assembly.
Angew Chem Int Ed Engl. 2003 Feb 24;42(8):934-6. doi: 10.1002/anie.200390248.
10
[Cd(II)(bpdc).H(2)O](n): a robust, thermally stable porous framework through a combination of a 2-D grid and a cadmium dicarboxylate cluster chain (H(2)bpdc = 2,2'-Bipyridyl-4,4'-dicarboxylic acid).[Cd(II)(bpdc)·H₂O]ₙ：一种通过二维网格和镉二羧酸簇链相结合形成的坚固、热稳定的多孔框架结构（H₂bpdc = 2,2'-联吡啶-4,4'-二羧酸）。
Inorg Chem. 2002 May 6;41(9):2592-7. doi: 10.1021/ic011192h.