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油麻藤饼的热重分析和分解动力学研究。

Thermogravimetric and decomposition kinetic studies of Mesua ferrea L. deoiled cake.

机构信息

Department of Energy, Tezpur University, Tezpur 784028, Assam, India.

出版信息

Bioresour Technol. 2013 Jul;139:66-72. doi: 10.1016/j.biortech.2013.03.191. Epub 2013 Apr 6.

DOI:10.1016/j.biortech.2013.03.191
PMID:23644072
Abstract

The present study aims to explore the physico-chemical properties of Mesua ferrea L. (Iron wood tree) deoiled cake (MFDC) and decomposition parameters for thermochemical methods of conversion. The physico-chemical characteristics of MFDC were investigated by bomb calorimetry, TG/DTA (10, 20 and 40°C min(-1)), elemental analysis (CHN) and FTIR spectroscopy. The proximate composition was calculated using standard ASTM methodology. The temperature profile, activation energy (E), pre-exponential factor (A) and reaction order (n) for the active pyrolysis zone of the species under investigation have been provided for the respective heating rates using Arrhenius, Coats-Redfern, Flynn-Wall-Ozawa (FWO) and Global independent reactions model. The current investigation suggests that within the realm of existing biomass conversion technologies, MFDC can be used as a feedstock for thermochemical conversion.

摘要

本研究旨在探索麻疯树(Mesua ferrea L.)脱油饼的物理化学性质及其用于热化学转化的分解参数。通过量热弹、TG/DTA(10、20 和 40°C min(-1))、元素分析(CHN)和傅里叶变换红外光谱法研究了 MFDC 的物理化学特性。使用标准 ASTM 方法计算了近似组成。使用 Arrhenius、Coats-Redfern、Flynn-Wall-Ozawa(FWO)和全局独立反应模型,针对所研究物种的活性热解区,为各加热速率提供了温度曲线、活化能(E)、前因子(A)和反应级数(n)。目前的研究表明,在现有的生物质转化技术范围内,MFDC 可以用作热化学转化的原料。

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