铁催化胺或醇与胺在空气中通过有氧氧化反应直接合成亚胺。
Iron-catalyzed direct synthesis of imines from amines or alcohols and amines via aerobic oxidative reactions under air.
机构信息
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, China.
出版信息
Org Lett. 2013 Jun 7;15(11):2704-7. doi: 10.1021/ol4010118. Epub 2013 May 17.
PMID:23683112
Abstract
Abundant and cheap iron readily catalyzed the aerobic oxidative reactions of primary amines, secondary amines, benzylamines with anilines, and alcohols with amines by directly using air as the economic and safe oxidant, providing several direct, practical, and greener approaches for the preparation of useful imines.
摘要
丰富且廉价的铁可直接利用空气作为经济且安全的氧化剂，容易催化伯胺、仲胺、苄胺与苯胺、醇与胺的有氧氧化反应，为有用的亚胺的制备提供了几种直接、实用且绿色的方法。
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