meso-无环 25-氧杂鲨烯素的 BF2 配合物的合成与功能化。
Synthesis and functionalization of BF2-complexes of meso-free 25-oxasmaragdyrin.
机构信息
Department of Chemistry, Indian Institute of Technology, Powai, Mumbai 400076, India.
出版信息
J Org Chem. 2013 Jun 21;78(12):6285-90. doi: 10.1021/jo400540u. Epub 2013 May 30.
PMID:23688239
Abstract
BF2-complex of meso-free 25-oxasmaragdyrin is synthesized under simple reaction conditions in high yield, and the reactivity of meso-free carbon atom was demonstrated by carrying out functionalization followed by coupling reactions.
摘要
在简单的反应条件下，高产率地合成了游离 25-氧杂尖杉脂素的 BF2 配合物，并通过官能化和偶联反应证明了游离碳原子的反应活性。
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