以羟基丙酮和 2-甲基呋喃合成可再生柴油。
Synthesis of renewable diesel with hydroxyacetone and 2-methyl-furan.
机构信息
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
出版信息
Chem Commun (Camb). 2013 Jun 28;49(51):5727-9. doi: 10.1039/c3cc42296h.
PMID:23694923
Abstract
Diesel or jet fuel range branched alkanes were synthesized for the first time by the combination of hydroxyalkylation-alkylation (HAA) of 2-methylfuran with hydroxyacetone and subsequent hydrodeoxygenation. Due to the electron-withdrawing effect of the hydroxyl group, the hydroxyacetone route exhibited evident advantages (higher HAA reactivity and diesel yield) over the previous acetone route.
摘要
首次通过 2-甲基呋喃与羟基丙酮的羟烷基化-烷基化（HAA）反应以及随后的加氢脱氧反应合成了柴油或喷气燃料范围支链烷烃。由于羟基的吸电子效应，与先前的丙酮路线相比，羟基丙酮路线表现出明显的优势（更高的 HAA 反应性和柴油收率）。
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