Wang Wei, Yan Jiamin, Sun Mengze, Li Xiufeng, Li Yanqing, An Ling, Qian Chi, Zhang Xing, Shao Xianzhao, Duan Yanping, Li Guangyi
Shaanxi Key Laboratory of Catalysis, School of Chemistry and Environment Science, Shaanxi University of Technology, Hanzhong 723001, China.
Hanzhong Institute of Agricultural Science, Hanzhong 723000, China.
Molecules. 2024 Jun 22;29(13):2976. doi: 10.3390/molecules29132976.
2-methylfuran is a significant organic chemical raw material which can be produced by hydrolysis, dehydration, and selective hydrogenation of biomass hemicellulose. 2-methylfuran can be converted into value-added chemicals and liquid fuels. This article reviews the latest progress in the synthesis of liquid fuel precursors through hydroxyalkylation/alkylation reactions of 2-methylfuran and biomass-derived carbonyl compounds in recent years. 2-methylfuran reacts with olefins through Diels-Alder reactions to produce chemicals, and 2-methylfuran reacts with anhydrides (or carboxylic acids) to produce acylated products. In the future application of 2-methylfuran, developing high value-added chemicals and high-density liquid fuels are two good research directions.
2-甲基呋喃是一种重要的有机化工原料，可通过生物质半纤维素的水解、脱水和选择性氢化反应制得。2-甲基呋喃能够转化为高附加值化学品和液体燃料。本文综述了近年来通过2-甲基呋喃与生物质衍生的羰基化合物的羟烷基化/烷基化反应合成液体燃料前驱体的最新进展。2-甲基呋喃通过狄尔斯-阿尔德反应与烯烃反应生成化学品，2-甲基呋喃与酸酐（或羧酸）反应生成酰化产物。在2-甲基呋喃的未来应用中，开发高附加值化学品和高密度液体燃料是两个良好的研究方向。
