氙单原子能成为手性的吗？
Can monoatomic xenon become chiral?
机构信息
Laboratoire de Chimie Organique CP 165/64, Université Libre de Bruxelles, 50 av FD Roosevelt, 1050 Bruxelles, Belgium.
出版信息
Chemphyschem. 2000 Dec 15;1(4):221-4. doi: 10.1002/1439-7641(20001215)1:4<221::AID-CPHC221>3.0.CO;2-E.
Abstract
A chiral host, cryptophane-A (1), makes even a monoatomic noble gas chiral. The interaction of xenon and 1 was monitored by (129) Xe NMR and in the presence of a chiral chemical shift reagent.
摘要
手性主体 cryptophane-A（1）可使单原子惰性气体呈现手性。通过（129）Xe NMR 监测氙气和 1 的相互作用，并在存在手性位移试剂的情况下进行监测。
相似文献
1
Can monoatomic xenon become chiral?
Chemphyschem. 2000 Dec 15;1(4):221-4. doi: 10.1002/1439-7641(20001215)1:4<221::AID-CPHC221>3.0.CO;2-E.
2
Effect of pH and counterions on the encapsulation properties of xenon in water-soluble cryptophanes.
Chemistry. 2010 Nov 15;16(43):12941-6. doi: 10.1002/chem.201001170.
3
Understanding a host-guest model system through ¹²⁹Xe NMR spectroscopic experiments and theoretical studies.
Angew Chem Int Ed Engl. 2014 Sep 8;53(37):9837-40. doi: 10.1002/anie.201405349. Epub 2014 Jul 22.
4
Utilizing a water-soluble cryptophane with fast xenon exchange rates for picomolar sensitivity NMR measurements.
Anal Chem. 2012 Nov 20;84(22):9935-41. doi: 10.1021/ac302347y. Epub 2012 Nov 6.
5
Degeneracy in cryptophane-xenon complex formation in aqueous solution.
Chem Commun (Camb). 2015 Jan 31;51(9):1721-4. doi: 10.1039/c4cc08601e.
6
Monomeric Cryptophane with Record-High Xe Affinity Gives Insights into Aggregation-Dependent Sensing.
Anal Chem. 2021 Jan 26;93(3):1507-1514. doi: 10.1021/acs.analchem.0c03776. Epub 2020 Dec 28.
7
Synthesis of a functionalizable water-soluble cryptophane-111.
Org Lett. 2013 Jun 7;15(11):2866-8. doi: 10.1021/ol4012019. Epub 2013 May 24.
8
Synthesis of enantiopure, trisubstituted cryptophane-A derivatives.
Org Lett. 2012 Jul 20;14(14):3580-3. doi: 10.1021/ol300943w. Epub 2012 Jul 11.
9
Fast gradient-encoded CEST spectroscopy of hyperpolarized xenon.
Chemphyschem. 2014 Feb 3;15(2):261-4. doi: 10.1002/cphc.201300888. Epub 2014 Jan 10.
10
Synthesis of Cryptophanes with Two Different Reaction Sites: Chemical Platforms for Xenon Biosensing.
J Org Chem. 2015 Jun 19;80(12):6143-51. doi: 10.1021/acs.joc.5b00653. Epub 2015 Jun 10.
Zotero 插件