Liu Sheng-Qiang, Yu Jun-Sheng, Zeng Yan-Bo, Zhao Juan, Du Chun-Lei
University of Electronic Science and Technology of China, Chengdu, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2013 Mar;33(3):636-41.
A white organic light-emitting device (WOLED) with a yellow phosphorescence material, bis[2-(4-tertbutylphenyl) benzothiazolato-N,C2 '] iridium (acetylacetonate) [(t-bt)2Ir(acac)], and two blue phosphorescence materials, iridium(Ill) bis (4', 6'-difluorophenylpyridinato) tetrakis(1-pyrazolyl) borate (FIr6) and bis[(4, 6-difluorophenyl)-pyridinato-N, C2 '] (picolinate) iridium (III) (FIrpic), were fabricated. Stable white emission was realized by using undoped ultrathin yellow emissive layer (EML), two doped blue EMLs together with the proper thickness of an interlayer confining the exciton. The WOLED performed pure white light emission with the Commissions Internationale de l'Eclairage (CIE) coordinates of (0.29+/-0.01, 0.34+/-0.01) from 6 to 14 V. Moreover, electroluminescence (EL) characteristics of the devices were also studied to verify the emissive mechanism from a phosphorescent system consisting of three iridium chelates. Also, the results showed that the triple-phosphor-element EMLs WOLED had lower efficiency roll-off owing to the stable recombination zone.
制备了一种白色有机发光器件(WOLED),其包含黄色磷光材料双[2-(4-叔丁基苯基)苯并噻唑-N,C2']铱(乙酰丙酮)[(t-bt)2Ir(acac)]以及两种蓝色磷光材料,铱(III)双(4',6'-二氟苯基吡啶基)四(1-吡唑基)硼酸酯(FIr6)和双[(4,6-二氟苯基)吡啶基-N,C2'](吡啶甲酸酯)铱(III)(FIrpic)。通过使用未掺杂的超薄黄色发光层(EML)、两个掺杂的蓝色EML以及具有合适厚度的限制激子的中间层,实现了稳定的白色发光。该WOLED在6至14V电压下以国际照明委员会(CIE)坐标(0.29±0.01,0.34±0.01)发出纯白光。此外,还研究了器件的电致发光(EL)特性,以验证由三种铱螯合物组成的磷光体系的发光机制。结果还表明,由于复合区稳定,三磷光元素EML的WOLED具有较低的效率滚降。