手性氨基酸氧肟酸盐构筑的反铁磁六核铜（II）轮的对映选择性自组装。
Enantioselective self-assembly of antiferromagnetic hexacopper(II) wheels with chiral amino acid oxamates.
机构信息
Departament de Química Inorgánica, Instituto de Ciencia Molecular (ICMOL), Universitat de Valéncia, 46980 Paterna, Valéncia, Spain.
出版信息
Chem Commun (Camb). 2013 Jul 7;49(53):5942-4. doi: 10.1039/c3cc42776e.
PMID:23715008
Abstract
The Cu(2+)-mediated self-assembly of oxamato-based ligands derived from either the (S)- or (R)-enantiomers of the amino acid valine leads to the formation of two antiferromagnetically coupled homochiral anionic hexacopper(II) wheels in the presence of templating tetramethylammonium countercations.
摘要
在模板四甲基铵抗衡阳离子存在的情况下，手性氨基酸缬氨酸的 (S)-或 (R)-对映异构体衍生的氧肟酸基配体的 Cu(2+)介导自组装导致形成两个反铁磁耦合的同手性阴离子六铜（II）轮。
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