Departament de Química Inorgánica, Instituto de Ciencia Molecular (ICMOL), Universitat de Valéncia, 46980 Paterna, Valéncia, Spain.
Chem Commun (Camb). 2013 Jul 7;49(53):5942-4. doi: 10.1039/c3cc42776e.
The Cu(2+)-mediated self-assembly of oxamato-based ligands derived from either the (S)- or (R)-enantiomers of the amino acid valine leads to the formation of two antiferromagnetically coupled homochiral anionic hexacopper(II) wheels in the presence of templating tetramethylammonium countercations.
在模板四甲基铵抗衡阳离子存在的情况下，手性氨基酸缬氨酸的 (S)-或 (R)-对映异构体衍生的氧肟酸基配体的 Cu(2+)介导自组装导致形成两个反铁磁耦合的同手性阴离子六铜（II）轮。
