尿素在金属有机骨架中修饰后作为一种催化活性氢键供体的多相催化剂。
Urea postmodified in a metal-organic framework as a catalytically active hydrogen-bond-donating heterogeneous catalyst.
机构信息
ZJU-ENS Joint Laboratory of Medicinal Chemistry, College of Pharmaceutical Sciences, Zhejiang University, Hangzhou, 310058, PR China.
出版信息
Chem Commun (Camb). 2013 Sep 11;49(70):7681-3. doi: 10.1039/c3cc42531b.
PMID:23715401
Abstract
New functionally diverse urea-derived MOF hydrogen-bond-donating heterogeneous catalysts were achieved via postsynthetic modification, which exhibit excellent catalytic activity and very broad substrate scopes for the Friedel-Crafts alkylation reactions.
摘要
通过后合成修饰，得到了具有新功能多样性的尿素衍生 MOF 氢键供体异相催化剂，其在 Friedel-Crafts 烷基化反应中表现出优异的催化活性和非常广泛的底物范围。
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