压力效应对异构轮烷合成的影响。

Pressure effects in the synthesis of isomeric rotaxanes.

机构信息

Department of Physics, Chemistry, and Pharmacy, University of Southern Denmark, Campusvej 55, DK-5230 Odense M, Denmark.

出版信息

Chem Commun (Camb). 2013 Jul 7;49(53):5936-8. doi: 10.1039/c3cc42201a.

DOI:10.1039/c3cc42201a

PMID:23719617

Abstract

Pressure not only influences the yield in the synthesis of a two-station [2]rotaxane, it also determines the distribution of the co-conformational isomers. At high pressure cyclobis(paraquat-p-phenylene) is preferentially assembled around a monopyrrolotetrathiafulvalene unit, while at low pressure it is preferentially assembled around a hydroquinone unit.

摘要

压力不仅影响[2]轮烷合成的产率，还决定了共构异构体的分布。在高压下，环双（对醌-对亚苯基）优先围绕一个单吡咯并四噻吩单元组装，而在低压下，它优先围绕一个对苯二酚单元组装。