Institute for Frontier Materials, Deakin University, Geelong, Victoria 3216, Australia.
Phys Chem Chem Phys. 2013 Jul 14;15(26):11106-12. doi: 10.1039/c3cp44312d. Epub 2013 May 30.
The photoinduced growth reaction of silver nanoparticles was accelerated by reduced graphene oxide (RGO) produced from graphene oxide (GO) during the light irradiation process in aqueous solution. X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy demonstrated that RGO was generated in the photoinduced process. The acceleration effect of RGO was investigated through monitoring the extinction spectra of silver nanoparticles during the synthesis process. Moreover, transmission electron microscopy (TEM) was employed to characterize the evolution of morphologies of silver nanoparticles at different irradiation times to demonstrate the effect of RGO. The results indicate that RGO accelerates the photoinduced synthesis of silver nanoparticles. It is proposed that the acceleration effect of RGO on the photoinduced reaction is attributed to the particular property of high electronic conductivity.
在水溶液的光照射过程中,氧化石墨烯(GO)还原生成的还原氧化石墨烯(RGO)加速了银纳米颗粒的光诱导生长反应。X 射线光电子能谱(XPS)和拉曼光谱表明,RGO 是在光诱导过程中产生的。通过监测银纳米颗粒在合成过程中的消光谱,研究了 RGO 的加速效应。此外,还采用透射电子显微镜(TEM)对不同照射时间下银纳米颗粒的形貌演变进行了表征,以证明 RGO 的作用。结果表明,RGO 加速了银纳米颗粒的光诱导合成。提出 RGO 对光诱导反应的加速作用归因于其高导电性的特殊性质。