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假对称 fac-二水-三氯[(二甲基磷酰基)甲铵-κO]锰(II)

Pseudosymmetric fac-di-aqua-trichlorido[(di-methyl-phosphor-yl)methanaminium-κO]manganese(II).

作者信息

Reiss Guido J

机构信息

Institut für Anorganische Chemie und Strukturchemie, Lehrstuhl II: Material- und Strukturforschung, Heinrich-Heine-Universität Düsseldorf, Universitätsstrasse 1, D-40225 Düsseldorf, Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 10;69(Pt 5):m250-1. doi: 10.1107/S1600536813008751. Print 2013 May 1.

DOI:10.1107/S1600536813008751
PMID:23723764
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3647798/
Abstract

In the title compound, [Mn(C3H11NOP)Cl3(H2O)2], the Mn(II) metal center has a distorted o-cta-hedral geometry, coordinated by the three chloride ligands showing a facial arrangement. Two water mol-ecules and the O-coordinated dpmaH cation [dpmaH = (di-methyl-phosphor-yl)methanaminium] complete the coordination sphere. Each complex mol-ecule is connected to its neighbours by O-H⋯Cl and N-H⋯Cl hydrogen bonds. Two of the chloride ligands and the two water ligands form a hydrogen-bonded polymeric sheet in the ab plane. Furthermore, these planes are connected to adjacent planes by hydrogen bonds from the aminium function of cationic dpmaH ligand. A pseudo-mirror plane perpendicular to the b axis in the chiral space group P21 is observed together with inversion twinning [ratio = 0.864 (5):0.136 (5)].

摘要

在标题化合物[Mn(C₃H₁₁NOP)Cl₃(H₂O)₂]中，Mn(II)金属中心具有扭曲的八面体几何构型，由呈面式排列的三个氯配体配位。两个水分子和O配位的dpmaH阳离子[dpmaH = (二甲基磷酰基)甲铵]完成配位球。每个配合物分子通过O—H⋯Cl和N—H⋯Cl氢键与其相邻分子相连。其中两个氯配体和两个水配体在ab平面形成氢键连接的聚合物片。此外，这些平面通过阳离子dpmaH配体铵功能的氢键与相邻平面相连。在手性空间群P2₁中观察到一个垂直于b轴的伪镜面以及倒转孪晶[比例 = 0.864 (5):0.136 (5)]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d48/3647798/a0cccd5d23ad/e-69-0m250-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d48/3647798/7b3dd5b72a4e/e-69-0m250-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d48/3647798/00458a9c8832/e-69-0m250-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d48/3647798/b355b80cf355/e-69-0m250-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d48/3647798/a0cccd5d23ad/e-69-0m250-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d48/3647798/7b3dd5b72a4e/e-69-0m250-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d48/3647798/00458a9c8832/e-69-0m250-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d48/3647798/b355b80cf355/e-69-0m250-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d48/3647798/a0cccd5d23ad/e-69-0m250-fig4.jpg

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