Jovita J V, Sathya S, Usha G, Vasanthi R, Sagayaraj P
PG and Research Department of Physics, Queen Mary's College, Chennai-4, Tamilnadu, India.
Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 13;69(Pt 5):o725. doi: 10.1107/S1600536813009410. Print 2013 May 1.
In the crystal of the title molecular salt, C7H10N(+)·C6H5O4S(-), the benzene-sulfonate units are linked through phenol-sulfonate O-H⋯O hydrogen bonds, forming chains along the c-axis direction. These chains are linked via N-H⋯O hydrogen bonds involving two of the three H atoms of the ammonium group of the 4-methyl-anilium cation, giving rise to two-dimensional networks parallel to the bc plane which are further connected through an additional N-H⋯O inter-action in which the third ammonium H atom is involved, generating a three-dimensional network.
在标题分子盐C7H10N(+)·C6H5O4S(-)的晶体中，苯磺酸盐单元通过酚磺酸盐O-H⋯O氢键相连，沿c轴方向形成链状结构。这些链通过涉及4-甲基苯胺阳离子铵基团三个H原子中的两个的N-H⋯O氢键相连，形成平行于bc平面的二维网络，该二维网络通过涉及第三个铵H原子的额外N-H⋯O相互作用进一步连接，从而生成三维网络。
