(1R,2S,5R)-(-)-薄荷基 (S)-2-(甲氧基羰基)苯亚磺酸盐
(1R,2S,5R)-(-)-Menthyl (S)-2-(methoxy-carbonyl)-benzene-sulfinate.
作者信息
Altamura Maria, Guidi Antonio, Jierry Loic, Paoli Paola, Rossi Patrizia
机构信息
Chemistry Department, Menarini Ricerche S.p.A., Via dei Sette Santi 3, I-50131 Firenze, Italy.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Apr 13;69(Pt 5):o731. doi: 10.1107/S1600536813009112. Print 2013 May 1.
In the title chiral sulfinic acid ester, C18H26O4S, the cyclo-hexane ring of the menthyl fragment adopts a chair conformation. The mol-ecular shape is defined by the dihedral angle of 47.87 (8)° between the mean planes of the cyclo-hexane and benzene rings. In the crystal, mol-ecules related by the screw axis are connected into chains along [010] by weak Car-H⋯O=S contacts.
在手性亚磺酸酯C18H26O4S的标题中，薄荷基片段的环己烷环呈椅式构象。分子形状由环己烷环和苯环平均平面之间47.87 (8)°的二面角确定。在晶体中，通过螺旋轴相关的分子通过弱的C—H⋯O=S接触沿[010]连接成链。
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