通过狄尔斯-阿尔德反应和臭氧氧化制备二羧酸型双子表面活性剂
Preparation of dicarboxylic acid-type gemini surfactant via Diels-Alder reaction & ozone oxidation.
作者信息
Chau Huynh N, Kawase Tokuzo, Oida Tatsuo
机构信息
Kyoto Institute of Technology, Laboratory of Interface Materials Kyoto-shi, Japan.
出版信息
J Oleo Sci. 2013;62(6):409-14. doi: 10.5650/jos.62.409.
PMID:23728332
Abstract
We wish to report a novel preparation method for Gemsurf analogs as well as dicarboxylic acid-type Gemini surfactant from Diels-Alder adducts of 2-trimethylsilyloxy-1,3-butadiene, in which ozone oxidation is adopted to convert C=C double bond to dicarboxylic acid without any additional oxidant.
摘要
我们希望报告一种由2-三甲基硅氧基-1,3-丁二烯的狄尔斯-阿尔德加合物制备宝石表面活性剂类似物以及二羧酸型双子表面活性剂的新方法，其中采用臭氧氧化将碳碳双键转化为二羧酸，无需任何额外的氧化剂。
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