Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA.
ACS Nano. 2013 Jun 25;7(6):4995-5007. doi: 10.1021/nn4003488. Epub 2013 Jun 3.
Light incident upon a periodically corrugated metal/dielectric interface can generate surface plasmon polariton (SPP) waves. This effect is used in many sensing applications. Similar metallodielectric nanostructures are used for light trapping in solar cells, but the gains are modest because SPP waves can be excited only at specific angles and with one linear polarization state of incident light. Here we report the optical absorptance of a metallic grating coupled to silicon oxide/oxynitride layers with a periodically varying refractive index, i.e., a 1D photonic crystal. These structures show a dramatic enhancement relative to those employing a homogeneous dielectric material. Multiple SPP waves can be activated, and both s- and p-polarized incident light can be efficiently trapped. Many SPP modes are weakly bound and display field enhancements that extend throughout the dielectric layers. These modes have significantly longer propagation lengths than the single SPP modes excited at the interface of a metallic grating and a uniform dielectric. These results suggest that metallic gratings coupled to photonic crystals could have utility for light trapping in photovoltaics, sensing, and other applications.
光照射在周期性波纹的金属/介电界面上会产生表面等离激元(SPP)波。这种效应在许多传感应用中都有使用。类似的金属-介电纳米结构也被用于太阳能电池中的光捕获,但增益效果并不显著,因为 SPP 波只能在特定角度和特定线性偏振态的入射光下被激发。在这里,我们报告了一种金属光栅与具有周期性折射率变化的氧化硅/氮氧化硅层的光学吸收率,即一维光子晶体。与使用均匀介电材料的结构相比,这些结构显示出了显著的增强效果。可以激活多个 SPP 波,并且 s 和 p 偏振的入射光都可以被有效地捕获。许多 SPP 模式的束缚较弱,并且显示出的场增强延伸到整个介电层。这些模式的传播长度比在金属光栅和均匀介电界面上激发的单个 SPP 模式长得多。这些结果表明,与光子晶体耦合的金属光栅在光捕获、传感和其他应用中可能具有实用价值。