Simon Fraser University, Department of Chemistry, 8888 University Drive, Burnaby, BC, Canada V5A 1S6.
Chemosphere. 2013 Sep;93(1):54-60. doi: 10.1016/j.chemosphere.2013.04.065. Epub 2013 May 31.
Some dialkoxybenzenes are promising new insect control agents. These compounds mimic naturally occurring odorants that modulate insect behavior. Before applying these compounds, however, their persistence and biodegradability at the application site and in the environment should be understood. The fate of organic compounds in the environment is a complex phenomenon which is influenced by many processes such as sorption to soil components, sedimentation, volatilization, and uptake by plants, as well as biotic and abiotic chemical degradation. In this study, the octanol-water partition coefficient, volatility and sorption on soil components (sand, clay and organic matter) of selected dialkoxybenzenes as well as structure activity relationships with regard to partition, volatility and sorption were investigated. Additionally, calculations of partition, molar volume and molecular surface areas were done, to understand structure-activity relationships of the physical properties.
一些二烷氧基苯是很有前途的新型昆虫控制剂。这些化合物模拟了调节昆虫行为的天然存在的气味物质。然而,在应用这些化合物之前,应该了解它们在应用地点和环境中的持久性和生物降解性。有机化合物在环境中的命运是一种复杂的现象,受许多过程的影响,如土壤成分的吸附、沉淀、挥发和植物的吸收,以及生物和非生物化学降解。在这项研究中,研究了选定的二烷氧基苯的辛醇-水分配系数、挥发性和对土壤成分(砂、粘土和有机物)的吸附,以及与分配、挥发性和吸附有关的结构-活性关系。此外,还进行了分配、摩尔体积和分子表面积的计算,以了解物理性质的结构-活性关系。