IC2MP, Institut de Chimie des Milieux et Matériaux de Poitiers, 4 rue Michel Brunet, 86000 Poitiers, France.
Bioresour Technol. 2013 Aug;142:1-8. doi: 10.1016/j.biortech.2013.04.123. Epub 2013 May 11.
An alternative fuel production was investigated through catalytic hydroliquefaction of three different carbonaceous sources: solid municipal wastes (MW), primary sludges (PS), and microalgae (MA). The reaction was carried out under hydrogen pressure, at different temperatures (330, 380 and 450°C), with a Raney nickel catalyst and two different hydrogen donor solvents: a "fossil solvent" (tetralin) and a "green solvent" (2-methyl-hydro-furan). The feeds analyses (TDA-TGA, ICP-AES, lipids quantification) showed that MW and PS had similar characteristics and physico-chemical properties, but different from those of MA. The hydroliquefaction of these feeds allowed to obtain high oil yields, with a significant energetic value, similar to that of a bio-petroleum. 2-methyl-hydro-furan was more efficient than tetralin for the treatment of the strongly bio-degraded biomasses MW and PS, while better results were obtained with tetralin in the case of MA.
固体城市废物（MW）、初级污泥（PS）和微藻（MA）。反应在氢气压力下、不同温度（330、380 和 450°C）下进行，使用雷尼镍催化剂和两种不同的氢供体溶剂：“化石溶剂”（四氢萘）和“绿色溶剂”（2-甲基-四氢呋喃）。进料分析（TDA-TGA、ICP-AES、脂质定量）表明，MW 和 PS 具有相似的特征和物理化学性质，但与 MA 不同。这些进料的加氢液化可以获得高油产率，具有显著的能量值，类似于生物石油。2-甲基-四氢呋喃比四氢萘更有效地处理强烈生物降解的生物质 MW 和 PS，而在 MA 的情况下，使用四氢萘可以获得更好的结果。
