3,4,6a,7,10,10a-六氢-7,10-环氧嘧啶并[2,1-a]异吲哚-6(2H)-酮与2-(2-氨基乙基)-3a,4,7,7a-四氢-1H-4,7-环氧异吲哚-1,3(2H)-二酮的比较：两种同源三环酰亚胺的结构与反应性差异
A comparison of 3,4,6a,7,10,10a-hexahydro-7,10-epoxypyrimido[2,1-a]isoindol-6(2H)-one and 2-(2-aminoethyl)-3a,4,7,7a-tetrahydro-1H-4,7-epoxyisoindole-1,3(2H)-dione: structural and reactivity differences of two homologous tricyclic imides.
作者信息
Mitchell Lauren A, Stanley Julie M, Espinosa De Hoyos Liliana, Holliday Bradley J
机构信息
Department of Chemistry and Biochemistry, The University of Texas at Austin, 105 E 24th Street, Stop A5300, Austin, TX 78712, USA.
出版信息
Acta Crystallogr C. 2013 Jun;69(Pt 6):638-41. doi: 10.1107/S0108270113010706. Epub 2013 May 2.
The crystal structures of 3,4,6a,7,10,10a-hexahydro-7,10-epoxypyrimido[2,1-a]isoindol-6(2H)-one, C11H12N2O2, and 2-(2-aminoethyl)-3a,4,7,7a-tetrahydro-1H-4,7-epoxyisoindole-1,3(2H)-dione, C10H12N2O3, two tricyclic imides, show one and two molecules in the asymmetric unit, respectively. Intermolecular hydrogen-bonding interactions are observed in both compounds.
3,4,6a,7,10,10a-六氢-7,10-环氧嘧啶并[2,1-a]异吲哚-6(2H)-酮（C11H12N2O2）和2-(2-氨基乙基)-3a,4,7,7a-四氢-1H-4,7-环氧异吲哚-1,3(2H)-二酮（C10H12N2O3）这两种三环酰亚胺的晶体结构分别在不对称单元中显示一个和两个分子。在这两种化合物中均观察到分子间氢键相互作用。
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