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本文引用的文献

1
Near-infrared-emitting phthalocyanines. A combined experimental and density functional theory study of the structural, optical, and photophysical properties of Pd(II) and Pt(II) α-butoxyphthalocyanines.近红外发光酞菁。钯(II)和铂(II)α-丁氧基酞菁的结构、光学和光物理性质的实验和密度泛函理论研究。
Inorg Chem. 2011 Feb 7;50(3):1135-49. doi: 10.1021/ic102209q. Epub 2010 Dec 28.
2
Photophysical behavior of open-shell first-row transition-metal octabutoxynaphthalocyanines: CoNc(OBu)8 and CuNc(OBu)8 as case studies.开壳层第一行过渡金属八丁氧基萘酞菁的光物理行为：以CoNc(OBu)8和CuNc(OBu)8为例进行研究。
Inorg Chem. 2008 May 19;47(10):4275-89. doi: 10.1021/ic7023204. Epub 2008 Apr 12.
3
On the photophysics of metallophthalocyanine-based photothermal sensitizers: synergism between theory and experiment.基于金属酞菁的光热敏化剂的光物理性质：理论与实验的协同作用
J Inorg Biochem. 2008 Mar;102(3):406-13. doi: 10.1016/j.jinorgbio.2007.10.029. Epub 2007 Nov 28.
4
Effects of benzoannulation and alpha-octabutoxy substitution on the photophysical behavior of nickel phthalocyanines: a combined experimental and DFT/TDDFT study.苯并环化和α-八丁氧基取代对镍酞菁光物理行为的影响：实验与DFT/TDDFT联合研究
Inorg Chem. 2007 Mar 19;46(6):2080-93. doi: 10.1021/ic061524o. Epub 2007 Feb 15.
5
Photophysics of octabutoxy phthalocyaninato-Ni(II) in toluene: ultrafast experiments and DFT/TDDFT studies.八丁氧基酞菁镍（II）在甲苯中的光物理性质：超快实验与密度泛函理论/含时密度泛函理论研究
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Photothermal sensitisation as a novel therapeutic approach for tumours: studies at the cellular and animal level.光热致敏作为一种新型肿瘤治疗方法：细胞和动物水平研究
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7
Quantification of the selective retention of palladium octabutoxynaphthalocyanine, a potential photothermal drug, in mouse tissues.对潜在光热药物八丁氧基萘酞菁钯在小鼠组织中的选择性滞留进行定量分析。
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Photo-properties of a silicon naphthalocyanine: a potential photosensitizer for photodynamic therapy.硅萘酞菁的光性质：一种用于光动力疗法的潜在光敏剂。
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Phthalocyanines as photosensitizers in biological systems and for the photodynamic therapy of tumors.酞菁作为生物系统中的光敏剂及用于肿瘤的光动力治疗。
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Quenching of singlet molecular oxygen by phthalocyanines and naphthalocyanines.酞菁和萘酞菁对单线态分子氧的猝灭作用。
Photochem Photobiol. 1992 May;55(5):691-6. doi: 10.1111/j.1751-1097.1992.tb08512.x.

一组过渡金属八丁氧基萘酞菁的合成与表征以及该组中钴、铑、铱、镍、钯和铂成员的吸收和发射特性

The Synthesis and Characterization of a Group of Transition Metal Octabutoxynaphthalocyanines and the Absorption and Emission Properties of the Co, Rh, Ir, Ni, Pd and Pt Members of This Group.

作者信息

Kim Junhwan, Soldatova Alexandra V, Rodgers Michael A J, Kenney Malcolm E

机构信息

Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106.

出版信息

Polyhedron. 2013 Jul 2;57:64-69. doi: 10.1016/j.poly.2013.04.022.

DOI:10.1016/j.poly.2013.04.022
PMID:23745014
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3670779/
Abstract

The synthesis and photophysical properties of new metallo-octabutoxynaphthalocyanines with Rh(III), Ir(III), and Pt(II) are reported. Various metals were inserted into the metal-free octabutoxynaphthalocyanine and the resultant metal complexes were fully characterized by NMR, UV-vis spectroscopy, and mass spectrometry. The absorption and emission properties of these new complexes were also examined and compared to those of Co(II), Ni(II), and Pd(II) octabutoxynaphthalocyanines. The results provide useful information to understand the effect of these transition metals on the properties of this macrocyclic ring.

摘要

报道了含铑（III）、铱（III）和铂（II）的新型金属八丁氧基萘酞菁的合成及其光物理性质。将各种金属引入无金属的八丁氧基萘酞菁中，所得金属配合物通过核磁共振、紫外可见光谱和质谱进行了全面表征。还研究了这些新型配合物的吸收和发射性质，并与钴（II）、镍（II）和钯（II）八丁氧基萘酞菁的性质进行了比较。这些结果为理解这些过渡金属对该大环环性质的影响提供了有用信息。