一组过渡金属八丁氧基萘酞菁的合成与表征以及该组中钴、铑、铱、镍、钯和铂成员的吸收和发射特性
The Synthesis and Characterization of a Group of Transition Metal Octabutoxynaphthalocyanines and the Absorption and Emission Properties of the Co, Rh, Ir, Ni, Pd and Pt Members of This Group.
作者信息
Kim Junhwan, Soldatova Alexandra V, Rodgers Michael A J, Kenney Malcolm E
机构信息
Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106.
出版信息
Polyhedron. 2013 Jul 2;57:64-69. doi: 10.1016/j.poly.2013.04.022.
Abstract
The synthesis and photophysical properties of new metallo-octabutoxynaphthalocyanines with Rh(III), Ir(III), and Pt(II) are reported. Various metals were inserted into the metal-free octabutoxynaphthalocyanine and the resultant metal complexes were fully characterized by NMR, UV-vis spectroscopy, and mass spectrometry. The absorption and emission properties of these new complexes were also examined and compared to those of Co(II), Ni(II), and Pd(II) octabutoxynaphthalocyanines. The results provide useful information to understand the effect of these transition metals on the properties of this macrocyclic ring.
摘要
报道了含铑（III）、铱（III）和铂（II）的新型金属八丁氧基萘酞菁的合成及其光物理性质。将各种金属引入无金属的八丁氧基萘酞菁中，所得金属配合物通过核磁共振、紫外可见光谱和质谱进行了全面表征。还研究了这些新型配合物的吸收和发射性质，并与钴（II）、镍（II）和钯（II）八丁氧基萘酞菁的性质进行了比较。这些结果为理解这些过渡金属对该大环环性质的影响提供了有用信息。
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